5-Chemistry-Organic-Chemical-Polymer

polymer

Molecules {polymer}| can link repeated subunits into sequence. Carbohydrates, proteins, and nucleic acids are polymers.

mass

Polymers have masses of 10,000 to 100,000 dalton. Masses have normal distribution, skewed toward lower masses. Centrifugation or light scattering can indicate mass.

osmotic pressure

Polymer osmotic pressure is higher than ideal solution pressure, because polymers are large molecules.

colloid

Polymers make colloids, because molecules are long.

viscosity

Polymer viscosity depends on molecule size and shape. Shape has four parameters: moments in three spatial dimensions and orientation.

plastic

Polymers {plastic, chemistry}| can have hydrocarbon subunits. Thermoplastics melt if heated. Thermosetting plastics do not melt if heated. Plastics can have covalent or hydrogen bonds that cross-link polymer chains.

types

Nitrocellulose was first plastic [1879] and comes from cellulose. It was in the first billiard balls and then in dental plates and Celluloid shirt collars. Nitrocellulose is in combs, brushes, eyeglass frames, film negatives, and car lacquer.

Cellulose acetate was second plastic invented, comes from cellulose, coats fabric-covered airplanes, is in model airplane glue, and is in nail polish, mixed with acetone.

Polyethylene comes from ethylene.

Polystyrene comes from styrene.

Polyvinyl chloride or PVC comes from vinyl chloride.

Acrylic comes from acrylonitrile.

Polyester comes from ethylene glycol and propylene glycol.

Nylon comes from amide.

elastomer

Polymers {elastomer} can stretch and then resume shape, because normally they are contracted chains. Elastic polymers have cis double bonds, to allow stretching.

cellophane

Nitrocellulose {cellophane} can be for wrapping.

rayon

Nitrocellulose {rayon} can be fibers.

viscose

Rayon and cellophane have basic units {viscose}.

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Date Modified: 2022.0225